The pictures come from a pre-order flyer at Toys R Us stores in Canada.
As you can see Sulley and Mr. Incredible are coming to stores on October 11th in single packs.
Buzz Lightyear, it appears at this time, will only come in the previously unknown Race to Space Play Set. Although they call it a Play Set, I do not think there will be anything new as far as missions go. It really is more of a Toy Set. The set will include Lightning McQueen, which was released on launch day, as well as the Buzz figure and two Power Discs. The two power discs included in the play set are: C.H.R.O.M.E. Damage Increaser (In-Game Weapons do 10% more damage) and Emperor Zurg’s Wrath (In-Game Weapons do 15% more damage). Both should be Toys R Us exclusive discs where they will have the 3-D sticker on it. This set will be released on November 1st.
It is important again to note that this is from a Canadian Toys R Us flyer, so you may not be able to pre-order in the United States and the dates could potentially be different.